Peat chemistry
Peat varies in nature according to the factors which produce differences in the vegetation of the mire surface, i.e. acidity/alkalinity and height of water table, both of which are affected by degree of human disturbance. Peat formed by acidophilous vegetation tends to have certain common features regardless of the type of mire. With a high water table, Sphagnum spp. are typically the important peat-forming plants, producing a fast-growing, loose-textured deposit known to peat-cutters as moss-litter. Where the mire surface is drier but still wet enough to prevent high humification, Sphagnum cover is reduced, and mono-cotyledonous plants such as Eriophorum vaginatum, E. angustifolium, Trichophorum cespitosum and Molinia caerulea are important peat-formers, producing a dense fibrous material. In former ages, the now very rare Scheuchseria palustris locally contributed a good deal to the formation of this fibrous peat, under conditions of high water table which were usually transitory. On still drier mire surfaces, dwarf shrubs such as Calluna vulgaris, Erica tetralix and Empetrum nigrum, along with Eriophorum vaginatum and Rhacomitrium lanuginosum contribute significantly to peat formation, but the greater rate of oxidation produces a more highly humified, amorphous deposit in which it is frequently more difficult to identify the remains of particular species.
In general, on ombrogenous mires, the shallower the depth of peat, the greater the degree of humification (and vice versa), and there is a gradual transition to the mor surface horizons of wet heaths as drainage improves. The peat most valued for fuel is that of relatively shallow, well-humified deposits. The peat of raised mires is often deep (up to 10 m), but the acidic material sometimes passes below into a fen peat laid down under mesotrophic or eutrophic conditions, and this in turn may overlie lake, fluvio-glacial or marine sediments. The remains of trees and shrubs, varying in size from twigs to large trunks, may occur at various levels, indicating periods when forest or scrub cover developed on the site. Though there is a general tendency for humification to increase towards the bottom of a deposit the deeper profiles of acidic peat are often stratified into layers of markedly differing humification, indicating changes in water table which may or may not be related to drier or wetter climatic phases. Often, too, deep peat-cuttings reveal the past small-scale surface structure of the mire, with systems of hummocks and hollows, either corresponding in position to similar features of the present day, or differing somewhat in their spatial relationships. The complete profile of a raised mire thus provides a unique record of the developmental history of the site, dating back in many instances to the period immediately following the end of the last Ice Age.
The peat of blanket mires differs from that of raised mires mainly in being shallower (not usually more than 5 m and most often from 2-4 m), and thus often more humified and generally in lacking underlying deposits formed under fen or open water conditions. Blanket mire is, however, variable in age; in many districts it evidently began to form widely at the onset of the Atlantic Period (around 5000 B.C.) as ground which carried forest or heath became waterlogged and soils impoverished under the wetter climate following the dry Boreal Period. Yet in many places, blanket mire did not begin to develop until much later; and topography, through its influence on drainage, appears to have been a crucial factor in the initiation of the process. There is also some evidence that blanket mire formation was accelerated in Neolithic times by human activities of forest clearance and stock grazing. Many blanket mires have peat with a basal layer containing remains of trees and tall shrubs which grew on the underlying mineral soil, typically of glacial drift. Some deposits contain tree remains at higher levels in the profile and, as in raised mires, the peat is usually stratified, with layers of differing humification reflecting vege-tational change according to variations in wetness of bog surfaces over long periods. These changes may sometimes be climatic, but it is again possible that some apparent changes in wetness may be the result of early human disturbance. Patterns of surface structure are again shown by the undulations of the horizons exposed in cut profiles. In many districts upland blanket peat is now subject to severe and widespread erosion, resulting in breakdown of the mire as a continuous system. This may be due to changing climatic conditions, or to inherent instability in the growth of blanket mire, but there is abundant stratigraphical evidence that heavy grazing and attendant land-use practices, especially burning, have played a part in initiating peat erosion.
Basin mires have often developed over kettle-holes and tend to have underlying deposits which are very deep, especially in relation to surface area. Some have basal lake sediments, and quite often the mire surface is a floating raft of vegetation (schwingmoor) overlying open water or semifluid peat. Where there is a deeper layer of more solid peat it tends to be like that of raised mires, except in the rather rare mesotrophic or eutrophic basin mires. The oligotrophic valley mires and soligenous mires tend to have rather shallow peats overlying the fluvial, fluvio- glacial or drift deposits of the channels, hollows and depressions where they occur. The peat is nevertheless often the unhumified moss-litter type, except at the shallow edges of a mire where there is a transition to the podsolic soils of dry ground. In some examples, especially of soligenous mires, there are good examples of peaty gley soils, and where periodic flooding of the surface occurs there may be varying mixtures of mineral sediment.
The open water transition and flood-plain mires, basin mires, valley mires and soligenous mires with poor-fen vegetation have peat formed from sedges or Sphagnum spp., or mixtures of these, varying again in humification between different places, and within the same profile. The mesotrophic and eutrophic examples with rich-fen vegetation generally have a distinctive peat formed from sedges and their allies, Phragmites communis and other tall grasses, forbs and ' brown mosses', in varying proportion. This peat tends to be moderately to highly humified, probably because higher pH allows some decomposition even under anaerobic conditions, but in open water transition and flood-plain mires the deposits are often quite deep (up to 8 m). When drained these rich-fen peats give agricultural soils of high fertility, as in the East Anglian Fenlands, but drying is accompanied by rapid oxidation and a tendency to wind-blow, so that over much of this district the land surface has shrunk by a depth of several metres, and in places the underlying clay is exposed. Conversely, the undrained remnants of the old Fenlands appear now as isolated blocks of peat forming more elevated islands, which can only be kept moist by artificial methods of maintaining water tables. Fen peat often contains the remains of alder and willow, indicating phases of carr development. In some localities, nuclei of oligotrophic vegetation amongst areas of rich-fen on the present surface may indicate incipient acidification of the kind which occurred on a large scale where flood-plain mire changed into raised mire.