Water
In the last half-century, as global population and food demand have more than doubled, and rivers and streams have become more polluted, we have increasingly turned to aquifers for drinking and irrigation water—and in the process, we have made a sobering discovery. Despite the popular impression that groundwater is shielded beneath our feet is not only susceptible to pollution, it is in many ways more vulnerable than water above ground.
Because water moves through the earth with glacial slowness, aquifers become sinks for pollutants, decade after decade. Some aquifers recharge fairly quickly, while others, like the Chalk, store their water for millennia. But the average residence time for groundwater is 1,400 years, as opposed to just 16 days for river water. So instead of being flushed out to the sea or becoming diluted with constant additions of fresh water, its pollutants accumulate. And in these sources, unlike rivers, the pollution is generally irreversible.
For most of human history, groundwater was tapped mainly in arid regions where surface water was in short supply.  In the second half of the twentieth century, the soaring demand for water turned the dowsers' modern-day counterparts into a major industry. Today, massive aquifers are tapped on every continent, and ground-water is the primary source of drinking water for 1.5-2 billion people worldwide.  The aquifer that lies beneath the Huang-Huai-Hai plain in eastern China alone supplies drinking water to nearly 160 million people. Some of the largest cities in the developing world— including Dhaka, Jakarta, Lima, and Mexico City—depend on aquifers for almost all their water. And in rural areas, where centralized supply systems are undeveloped, groundwater is typically the sole source of water. Almost 99 percent of the rural U.S. population and 80 percent of rural Indians depend on groundwater for drinking.
A principal reason for the explosive rise in groundwater use since 1950 has been a dramatic expansion in irrigated agriculture. In fact, irrigation accounts for about two thirds of the fresh water drawn from rivers and wells each year. In India, the leading country in total irrigated area and the world's third largest grain producer, the number of shallow tubewells used to draw groundwater surged from 3,000 in 1950 to 6 million in 1990. Today aquifers supply water to more than half of India's irrigated land. About 40 percent of India's agricultural output comes from areas irrigated with groundwater.
Some major threats to 'drinking quality' grandwater
Threat
Sources
Effects
Region at risk
Nitrates
Fertilizer runoff; manure from livestock operations; septic systems
Restricts amount of oxygen reaching brain, which can cause death in infants ("blue-baby syndrome"); linked to digestive tract and other cancers; causes algal blooms and eutrophication in surface waters
Parts of midwestern and mid-Atlantic United States, north China plain, northern India, parts of Eastern Europe
Pesticides
Runoff from farms, backyards, golf courses; landfill leaks
Organochlorines linked to reproductive and endocrine disorders in wildlife; organophosphates and carbamates linked to nervous system damage and cancers
Parts of United States, China, India
Petro- chemicals
Underground petroleum storage tanks 
Benzene and other petrochemicals can be cancer- causing even at low exposure
United States, United Kingdom, parts of former Soviet Union
Chlorinated solvents
Metals and plastics degreasing; fabric cleaning; electronics and aircraft manufacture
Linked to reproductive disorders and some cancers
California, industrial zones in East Asia
Arsenic
Naturally occurring
Nervous system and liver damage; skin cancers
Bangladesh,West Bengal, India, Nepal, Taiwan
Other heavy metals
Nervous system and kidney metals landfills; hazardous waste dumps
Nervous system and kidney damage; metabolic disruption
United States, Central America, Eastern Europe
Radioactive materials
Nuclear testing and medical waste.
Increased risk of certain cancers.
Western United States, parts of former Soviet Union
Fluoride
Naturally occurring
Dental problems; crippling spinal and bone damage
Northern China, northwestern India; parts of Sri Lanka, Thailand, and East Africa
Salts
Sea water intrusion
Freshwate unusable for drinking an irrigation
Coastal China and India, Gulf coasts of Mexico and Florida, Australia.Thailand